Main Types of Refractory Materials for Electric Arc Furnaces

Electric arc furnaces (EAFs) operate under extremely harsh conditions, including ultra-high temperatures, intense thermal shock, chemical corrosion from slag and molten steel, mechanical abrasion, and strong electromagnetic and arc radiation. As a result, the selection of refractory materials for electric furnaces plays a decisive role in furnace performance, operational stability, energy efficiency, and overall service life.

Modern electric furnace refractory systems are no longer based on a single material. Instead, they are composed of a complete set of specialized refractory products designed for different furnace zones and operating conditions. This article provides a comprehensive overview of the main types of refractory materials for electric arc furnaces, their structural characteristics, performance advantages, and typical applications.

Choose Refractory Bricks for Electric Arc Furnaces

1. Electric Furnace Purging Plugs

Electric furnace purging plugs are typically designed as metal tube–magnesia carbon brick composite structures. Their primary function is to ensure stable and efficient bottom stirring or combined top-and-bottom blowing during electric arc furnace steelmaking.

Structural Characteristics

  • The gas channels are constructed from heat-resistant stainless steel tubes, commonly with dimensions of φ3×1 mm or φ4×1 mm, ensuring reliable gas delivery under high-temperature conditions.

  • Depending on the plug size and furnace design, each purging plug may contain between 10 and 100 stainless steel tubes, providing sufficient gas flow capacity.

  • The matrix material consists of a high-quality magnesia carbon brick, allowing the purging plug to achieve a service life synchronized with that of the furnace bottom lining.

Performance Advantages

  • High gas permeability with uniform and stable airflow distribution

  • Excellent blowing efficiency under properly controlled operating conditions

  • Reliable performance for EAF combined top-and-bottom blowing processes

  • Strong resistance to thermal shock and molten steel erosion

Due to the high number of metal tubes and the optimized internal layout, electric furnace purging plugs deliver high gas blow-through rates and consistent stirring performance, making them indispensable components in modern electric arc furnace bottom systems.

Ladle Purging Plug Production Details

2. Magnesia Carbon Bricks for Electric Furnaces

Magnesia carbon bricks are among the most widely used refractory materials for electric arc furnaces. They are carefully engineered according to different furnace zones and operating environments.

Raw Material Composition

  • High-purity, high-density fused magnesia

  • Large-crystal fused magnesia

  • High-purity graphite

  • Appropriate amounts of metallic antioxidants

  • Phenolic resin as the bonding agent

Key Properties

  • Excellent resistance to slag corrosion

  • Strong resistance to thermal shock

  • High mechanical strength at elevated temperatures

  • Low wettability with molten steel and slag

Different grades of magnesia carbon bricks are selected for various furnace positions, such as furnace walls, slag lines, and hearth zones, based on specific metallurgical conditions. Their balanced performance makes them a cornerstone of EAF refractory lining systems.

Successful Export of Magnesia-Carbon Bricks to the USA

3. Electric Furnace Roof and Ladle Refining Furnace Roof Refractories

Electric furnace roofs and refining furnace roofs are exposed to some of the most aggressive conditions in steelmaking operations.

Operating Challenges

  • Frequent and severe thermal shock

  • Chemical corrosion from slag and furnace gases (CO, CO₂, SO₂)

  • Intense radiation from high-temperature electric arcs

  • High-speed gas flow erosion caused by dust extraction systems

Material Design Concept

To meet these challenges, roof refractories are formulated using:

  • Cement-bonded or non-cement bonded systems

  • Ultrafine powder technology

  • High-performance binders and chemical additives

  • Scientifically optimized particle size distribution

Each formulation is precisely adjusted according to the furnace type, power level, and operating conditions.

Performance Characteristics

  • Outstanding thermal shock resistance

  • Strong resistance to slag and gas corrosion

  • Excellent volume stability

  • Extended service life

The PN series electric furnace and refining furnace roof products manufactured by Puyang Refractories are suitable for:

  • Conventional EAFs

  • Ultra-high power (UHP) electric arc furnaces

  • Ladle refining furnaces

  • VD (Vacuum Degassing) furnaces

4. Electric Furnace Tapping Spouts

The tapping spout is a critical component in electric furnace steelmaking, directly affecting tapping safety and efficiency.

Material Structure

  • Large-crystal fused magnesia

  • High-purity graphite

  • Metallic antioxidants

  • Phenolic resin binder

Manufacturing Methods

  • Cold isostatic pressing (for integral tapping spouts)

  • Mechanical pressing (for segmented tapping spouts)

Key Advantages

  • Excellent oxidation resistance

  • High mechanical strength

  • Strong resistance to steel and slag erosion

  • Easy replacement and maintenance

  • Long service life

These tapping spouts are designed to withstand repeated thermal cycles and aggressive molten steel flow without premature failure.

5. Tapping Hole Filling Materials

Tapping hole filling materials play a vital role in ensuring automatic tapping and preventing molten steel leakage during EAF operations.

Working Principle

  • During smelting, the filling material in contact with molten steel forms a sintered layer, effectively blocking steel penetration.

  • Beneath the sintered layer, the unsintered material remains loose.

  • When the slide gate is opened for tapping, the loose material flows out smoothly.

  • Under steel pressure, the sintered layer breaks, enabling automatic opening of the tapping hole.

Performance Features

  • Non-floating behavior

  • High automatic opening rate

  • Simple operation

  • Safe use

  • No contamination of molten steel

These materials are widely used in electric furnace tapping systems and contribute significantly to operational safety and efficiency.

6. Dry Ramming Mix for Electric Furnace Bottoms

Dry ramming mixes are specially developed for HP and UHP electric furnace bottoms, where resistance to molten steel penetration and erosion is critical.

Design Principles

  • Based on the principle of maximum particle packing density

  • Made from high-quality synthetic raw materials

  • Combined with specialized additives and binders

Advantages

  • Strong resistance to molten steel infiltration

  • Excellent erosion resistance

  • Easy sintering during operation

  • High bulk density after ramming

  • Convenient and efficient installation

Dry ramming mixes provide a dense and durable furnace bottom lining, contributing to stable furnace performance and reduced maintenance frequency.

7. Electric Furnace Gunning Repair Materials

Gunning repair materials are designed for both cold and hot repairs of electric furnace linings.

Raw Materials and Composition

  • High-quality magnesia

  • Magnesia-calcia materials

  • Dolomite

  • Unique binders and additives

Performance Characteristics

  • High adhesion strength

  • Low rebound rate during spraying

  • Easy sintering

  • Strong resistance to scouring and erosion

  • Excellent corrosion resistance

These materials are ideal for quick and effective repairs of furnace walls, slag lines, and other critical areas, minimizing downtime and extending lining life.

Refractory Materials for Electric Arc Furnaces

8. Hot Repair Materials for Tapping Spouts and Furnace Bottoms

Hot repair materials are essential for localized hot-state maintenance during EAF steelmaking operations.

Typical Applications

  • Filling gaps between sleeve bricks and furnace bottoms when replacing tapping spouts

  • Repairing localized pits or cracks in furnace bottoms without cooling down the furnace

Material Characteristics

  • Made from high-iron, high-calcium magnesia raw materials

  • Combined with unique organic binders

Key Benefits

  • Rapid strength development at low temperatures

  • High strength at elevated temperatures

  • Excellent resistance to scouring and corrosion

These hot repair materials allow steel plants to perform efficient maintenance without interrupting production cycles.

Conclusion

The refractory materials used in electric arc furnaces form a highly integrated system, where each product serves a specific function under extreme operating conditions. From gas permeable bricks and magnesia carbon bricks to furnace roofs, tapping spouts, ramming mixes, and repair materials, every refractory component contributes to furnace efficiency, safety, and longevity.

Selecting the right refractory materials for electric furnaces requires not only an understanding of material properties but also a deep knowledge of steelmaking processes and operating conditions. By using well-designed, application-specific refractory solutions, steel producers can significantly improve furnace performance, reduce refractory consumption, and achieve more stable and cost-effective operations.

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